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The decomposition of IT-4F by 2-DMAP was carefully proved to be via retro-aldol condensation. As a result, the device (PBDBT-FIT-4F) modified with 2-DMAP displayed a low PCE of 7.34%. The zwitterionic PAS with reduced nucleophilicity and basicity can modify the ITO surface without decomposing IT-4F. The PBDBT-FIT-4F-based device modified with PAS maintained a high PCE of 11.41%. Most importantly, the PAS-based device using the well-known Y6 acceptor (PBDBT-FY6) can achieve a PCE of 13.82%. This new interfacial material can be universally applied to I-OSCs employing various A-D-A-type acceptors installed with the electrophilic 1,1-dicyanamethylene-5,6-difluoro-3-indanone (FIC) end-group.Block copolymer electrolytes (BCE) such as polystyrene-block-poly(ethylene oxide) (SEO) blended with lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) and composed of mechanically robust insulating and rubbery conducting nanodomains are promising solid-state electrolytes for Li batteries. Here, we compare ionic solvation, association, distribution, and conductivity in SEO-LiTFSI BCEs and their homopolymer PEO-LiTFSI analogs toward a fundamental understanding of the maximum in conductivity and transport mechanisms as a function of salt concentration. Ionic conductivity measurements reveal that SEO-LiTFSI and PEO-LiTFSI exhibit similar behaviors up to a Li/EO ratio of 1/12, where roughly half of the available solvation sites in the system are filled, and conductivity is maximized. As the Li/EO ratios increase to 1/5 the conductivity, of the PEO-LiTFSI drops nearly 3-fold, while the conductivity of SEO-LiTFSI remains constant. FTIR spectroscopy reveals that additional Li cations in the homopolymer electrolyte are complexed by additional EO units when the Li/EO ratio exceeds 1/12, while in the BCE, the proportion of complexed and uncomplexed EO units remains constant; Raman spectroscopy data at the same concentrations show that Li cations in the SEO-LiTFSI samples tend to coordinate more to their counteranions. Atomistic-scale molecular dynamics simulations corroborate these results and further show that associated ions tend to segregate to the SEO-LiTFSI domain interfaces. The opportunity for "excess" salt to be sequestered at BCE interfaces results in the retention of an optimum ratio of uncompleted and complexed PEO solvation sites in the middle of the conductive nanodomains of the BCE and maximized conductivity over a broad range of salt concentrations.The asymmetric allylic alkylation (AAA) of achiral Morita-Baylis-Hillman (MBH) carbonates with 3,3'-bisindolines under the catalysis of amino-acid-derived bifunctional phosphines was accomplished. With the AAA approach introduced herein, challenging 3,3'-bisindolines bearing an all-carbon quaternary stereocenter (C3a) have been constructed in good yields with good to excellent enantioselectivties. In addition, the synthetic value of this protocol was demonstrated by the facile synthesis of the core skeleton of gliocladin C.We demonstrate how the singlet fission process in pentacene dimers mediated by a conical intersection is controlled by coupling the molecule to a confined optical cavity photon mode. By following the polariton quantum dynamics of a conical intersection coupled to a cavity mode taking into account vibrational relaxation and cavity loss, we find that the singlet fission can be significantly suppressed because the polaritonic conical intersection is pushed away from the initial Franck-Condon excitation region.Dwellings are material intensive products. To date, material use in dwellings has been investigated mainly using economic (exogenous) or dwelling (endogenous) drivers, with few studies comprehensively combining both. For the first time, we identify a comprehensive set of such drivers of demand for building materials and analyze them using the logarithmic mean divisia index (LMDI) method. We combine the LMDI method, the concept of dynamic material flow analysis, and physical and monetary flows to decompose the demand for building materials into the following six effects material intensity, floor area shape, dwelling type, dwelling intensity, economic output, and population. We analyze these six effects on demand for concrete in new dwellings in the U.K. from 1951 to 2014, classified into six dwelling types and four subregions. Of these six effects, the material intensity effect is the most important, overall contributing to increasing concrete demand by +79 Mt from 1950 to 2014, while the dwelling intensity effect plays an opposite role, overall reducing concrete demand from 1950 to 2014 by -56 Mt. The economic output effect is also significant (+38 Mt from 1950 to 2014). A comparative analysis of the six effects in the four U.K. nations reveals that most of the effects arise from England, while the other nations have minor effects due to their smaller populations. Our results show that changes to the demand for concrete in the U.K. fluctuate and have mainly remained between ±30 Mt year-2 from 1950 to 2014, and thus the inflows of concrete into the in-use stock of dwellings have experienced neither entirely increasing or decreasing trends during this period. This study contributes to understanding changes in resource demand due to social, economic, and technological factors and thus improves the capability to reliably and quantitatively model the use of materials in the built environment.Transition-metal oxide nanostructured materials are potentially attractive alternatives as anodes for Li ion batteries and as photocatalysts. Combining the structural and thermal stability of titanium oxides with the relatively high oxidation potential and charge capacity of molybdenum(VI) oxides was the motivation for a search for approaches to mixed oxides of these two metals. Challenges in traditional synthetic methods for such materials made development of a soft chemistry single-source precursor pathway our priority. A series of bimetallic Ti-Mo alkoxides were produced by reactions of homometallic species in a 11 ratio. Thermal solution reduction with subsequent reoxidation by dry air offered in minor yields Ti2Mo2O4(OMe)6(OiPr)6 (1) by the interaction of Ti(OiPr)4 with MoO(OMe)4 and Ti6Mo6O22(OiPr)16(iPrOH)2 (2) by the reaction of Ti(OiPr)4 with MoO(OiPr)4. An attempt to improve the yield of 2 by microhydrolysis, using the addition of stoichiometric amounts of water, resulted in the formation with high yield of a different complex, Mo7Ti7+xO31+x(OiPr)8+2x (3). Controlled thermal decomposition of 1-3 in air resulted in their transformation into the phase TiMoO5 (4) with an orthorhombic structure in space group Pnma, as determined by a Rietveld refinement. The electrochemical characteristics of 4 and its chemical transformation on Li insertion were investigated, showing its potential as a promising anode material for Li ion batteries for the first time. A lower charge capacity and lower stability were observed for its application as an anode for a Na ion battery.Controlling the dynamic imine bonds upon a novel trigger except for pH and temperature is still a significant challenge. Here, a Se-containing imine-based dynamic covalent surfactant (HOBAB-BSeEA) was developed for the first time by mixing two precursors in situ an asymmetric double-chain cationic surfactant bearing a formyl group at the terminal of one hydrophobic tail and a Se-containing amine (2-(benzylselanyl)ethan-1-amine) in order to confirm the effect of redox on the imine bonds. The imine bond in HOBAB-BSeEA can be regulated not only upon changing the pH as well as other common imine-based surfactants but also by oxidation. The conversion efficiency of imine bonds is closely related with the degree of oxidation and pH. Complete oxidation can decrease the conversion efficiency from ∼87 to 48%, which is comparable to the result of changing the pH from 10.0 to 7.0. With the formation and breaking of imine bonds, the surfactant can be reversibly switched between symmetric and asymmetric structures, accompanied by a morphological transition from vesicles to spherical micelles. Although oxidation cannot demolish all imine bonds, it can completely convert vesicles to spherical micelles, which is mainly ascribed to an increase in the polarity of the micellar microenvironment stemming from the oxidation of Se. However, this transition can only be achieved by reducing the pH to 5.0 instead of 7.0. Nile red loaded in HOBAB-BSeEA vesicles can be quickly, controllably, and step-by-step released upon oxidation stimulus but not pH. Understanding the mechanism of oxidation-induced breakage of imine bonds and disruption of vesicles would be useful in designing redox-responsive imine-based carriers that can unload cargoes according to the level of the local reactive oxygen species.Photocatalytic CO2 reduction reaction is believed to be a promising approach for CO2 utilization. In this work, a noble metal-free photocatalytic system, composed of bis(terpyridine)iron(II) complexes and an organic thermally activated delayed fluorescence compound, has been developed for selective reduction of CO2 to CO with a maximum turnover number up to 6320, 99.4% selectivity, and turnover frequency of 127 min-1 under visible-light irradiation in dimethylformamide/H2O solution. More than 0.3 mmol CO was generated using 0.05 μmol catalyst after 2 h of light irradiation. The apparent quantum yield was found to be 9.5% at 440 nm (180 mW cm-2). Control experiments and UV-vis-NIR spectroscopy studies further demonstrated that water strongly promoted the photocatalytic cycle and terpyridine ligands rather than Fe(II) were initially reduced during the photocatalytic process.Epitaxial growth of aluminum gallium oxide is important for forming heterojunctions on Ga2O3 for high power electronics applications. We use density functional theory to explore the co-adsorption of Al, Ga, and O adatoms on the Ga2O3(010) surface and the surface reconstructions during the growth of the alloy. [https://www.selleckchem.com/products/alw-ii-41-27.html Protein Tyrosine Kinase inhibitor] We find that Al can adsorb in tetrahedral sites in many of the reconstructions. The migration barrier escaping from a tetrahedral site to an octahedral site is 1.72 eV for an Al adatom and 0.56 eV for a Ga adatom, indicating that Al diffusion is much more restricted than Ga diffusion on the surface. Our findings indicate that kinetic limitations are responsible for Al occupying both octahedral and tetrahedral sites in (AlxGa1-x)2O3, in spite of the fact that thermodynamically the octahedral site is preferred.New iodoargentate hybrids containing lanthanide complexes, [La(DMA)8]Ag9I12·2H2O (1) and [Ln(DMA)7]2Ag16I22 (Ln = Pr (2), Sm(3); DMA = N,N-dimethylacetamide), were prepared by diffusion methods using DMA-solvated lanthanide complexes as structure-directing agents. The octakis-solvated La3+ cation leads to formation of the 1-D nonanuclear [Ag9I12]n3n- polymeric anion constructed by AgI4 tetrahedral units through edge sharing, while the heptakis-solvated Ln3+ (Ln = Pr, Sm) cation affords the new 1-D hexadecanuclear [Ag16I22]n6n- polymeric anion built up from AgI4 units by both corner and edge sharing. Compounds 1-3 possess band gaps of 2.58, 2.77, and 2.74 eV, respectively, and show steady photocurrents in the range 14.2-18.0 μA under Xe light irradiation. They are photocatalytic active in the degradation of organic pollutants of crystal violet (CV) and rhodamine B (RhB) in water at room temperature. 2 and 3 perform higher photocatalytic activities than 1 in the CV degradation, which is attributed to the different photocurrent intensities.