Haemangiomas in the urinary system kidney Two scenario studies

The obtained PDMAEMA nanogel exhibits dual-responses to pH and salt, which allow manipulation of the positive charges of the nanogels for selective loading and controlled release of anionic substances; we demonstrate this with an anionic dye. The study presented here fully addresses the process parameters of EADP regarding optimal and controlled preparation of PE nanogels, which should allow exploration of their potential vis-a-vis a variety of applications.The rhythmic beating motion of autonomously motile filaments has many practical applications. Here, we present an experimental study on a filament made of camphor infused paper disks, stitched together adjacent to each other using nylon thread. The filament displays spontaneous translatory motion when it is placed on the surface of water due to the surface tension gradients created by camphor molecules on the water surface. When this filament is clamped on one end, we obtain regular oscillatory motion instead of translation. The filament shows qualitatively different dynamics at different activity levels, which is controlled by the amount of camphor infused into the paper disks. For a better physical understanding of the filament dynamics, we develop a minimal numerical model involving a semi-flexible filament made of active polar disks, where the polarity is coupled to the instantaneous velocity of the particle. This model qualitatively reproduces different oscillatory modes of the filament. Moreover, our model reveals a rich dynamical state diagram of the system, as a function of filament activity and the coupling strength.Capillarity driven self-assembly is a way to create spontaneous structures along liquid interfaces in between bottom-up and top-down fabrication methods. Based on multipolar capillary interactions between elementary floating object, simple to complex structures can been achieved by designing objects with specific 3D shapes. We show herein that a switchable self-assembled structure can be obtained with a shape memory polymer. At a defined temperature of the liquid, the 3D shape of each elementary floating object changes, modifying the capillary interactions thus forcing the stable structure to disassemble and to form a new arrangement. Based on simulations and experiments, we study how this cooperative behavior induces metastable complex configurations.Mixtures of water and PEG exhibit a well known eutectic phase diagram. While the thermodynamic properties like eutectic and liquidus temperatures as well as the eutectic concentration are intensely investigated almost nothing is known about the structural properties of water and PEG in the different regions of the phase diagram. Therefore, we report on a combined DSC, SAXS and WAXS study over the full range of polymer water compositions in order to elucidate the crystalline and semi-crystalline structure. Throughout the whole phase diagram no signatures of a mixed-crystalline phase of PEG and water can be found. Below the eutectic temperature, both components demix microscopically into hexagonal ice and crystalline PEG with its well known crystalline structure. In the region between eutectic and liquidus temperature, the solid component is composed of a single phase of either pure semi-crystalline PEG (PEG rich side of the phase diagram) or pure ice (water rich side). The semi-crystalline structure of PEG, in contrast, is changed by the presence of water. Its long spacing dac increases due to the incorporation of water molecules in the amorphous regions, while the formation of crystalline regions seems to be enhanced, resulting in an almost unaffected crystallinity.We experimentally investigate the spreading and receding behavior of small water droplets immersed in viscous oils on grid-patterned surfaces using synchronized bottom and profile views. In particular, the evolution of apparent advancing and receding contact angles of droplets fed at constant flow rate is studied as a function of grid surface coverage and height for a wide range of external phase viscosity. Detailed examination of droplet aspect ratio during inflation process provides an averaging method for characterization of quasi-static advancing angles on heterogeneous surfaces. Droplets spreading in partial Cassie state on planar microfluidic grids are also shown to capture oil patches that further evolve into trapped oil droplets depending on grid aspect ratio. The natural retraction velocity of thin water films is examined based on external phase velocity and regime maps of trapped droplets are delineated based on control parameters.Correction for 'Regioselective synthesis of substituted thiazoles via cascade reactions from 3-chlorochromones and thioamides' by Tianzi Dai et al., Org. Biomol. learn more Chem., 2020, 18, 6162-6170, DOI .In drying liquid films of polymer-colloid mixtures, stratification in which polymers are placed on top of larger colloids is studied. It is often presumed that the formation of segregated polymer-colloid layers is solely due to the proportion in size at fast evaporation as in binary colloid mixtures. By comparing experiments with a theoretical model, we found that the transition in viscosity near the drying interface was another important parameter for controlling the formation of stratified layers in polymer-colloid mixtures. At high evaporation rates, increased polymer concentrations near the surface lead to a phase transition from a semidilute to concentrated regime, in which colloidal particles are kinetically arrested. Stratification only occurs if the formation of a stratified layer precedes the evolution to the concentrated regime near the drying interfaces. Otherwise, the colloids will be trapped by the polymers in the concentrated regime before forming a segregated layer. Also, no stratification is observed if the initial polymer concentration is too low to form a sufficiently high polymer concentration gradient within a short period of time. Our findings are relevant for developing solution-cast polymer composites for painting, antifouling and antireflective coatings.Aluminum is a plasmonic material well known for its excellent stability, complementary metal-oxide-semiconductor compatibility and wide availability as compared to popular plasmonic materials such as gold and silver. Aluminum can support surface plasmon resonances in a broad spectral range, including the deep ultra-violet, a regime where no other plasmonic materials can work. However, conventional aluminum films suffer from high losses in the visible region and low fidelity and reproducibility in nanofabrication, making aluminum plasmonics non-ideal for applications. Herein, we report the experimental results of consistent surface plasmon propagation length measurements for epitaxially grown aluminum and silver films (epifilms), using three different methods (white light interferometry, laser scattering and spectroscopic ellipsometry) in the full visible spectrum. In order to avoid losses caused by inferior material quality, we used single-crystalline aluminum and silver films for direct comparison. We found that, on directly comparing with the silver epifilm, the aluminum epifilm possesses reasonably long plasmon propagation lengths in the full visible range and outperforms silver in the deep blue region.