A emotional wellbeing platform from the sounds associated with refugees

The substrates coated with Parylene C that were soaked in 10% ammonium hydroxide exhibited high surface roughness. The aforementioned results indicate that 3D-printed photopolymers coated with Parylene C can offer potential benefits when used in biocompatible devices.The generation of waste tires is rapidly increasing. Waste tire pyrolysis is an alternative to waste tire recycling. The main substances extracted in the waste tire pyrolysis method include oil, carbon black, and iron. In this study, carbon black from the pyrolysis of waste tires was used to modify and improve the permanent deformation properties of the asphalt binder, and 0%, 5%, 10%, 15%, and 20% of pyrolysis carbon black by weight were mixed in raw asphalt, which is called AP-3 and AP-5. Laboratory tests, such as the softening point test, flash point test, rotational viscometer test, dynamic shear rheometer test, and bending beam rheometer test, were carried out. The use of pyrolysis carbon black increased the softening point and rotational viscosity at 135 °C. When using 15% PCB for AP-3 and 10% PCB for AP-5, the performance improvement effect of the resistance to permanent deformation was significant. The use of pyrolysis carbon black decreased fatigue at room temperature and improved the resistance of low-temperature cracking up to -12 °C but gave poor results at -18 °C.In this study, we comparatively study the microstructures and mechanical properties of prequenching-quenching and partitioning (QQ&P) and traditional Q&P samples at different annealing temperatures (intercritical annealing temperatures). When the annealing temperature is 780 °C, the ferrite and retained austenite in QQ&P samples with lath and blocky morphologies. The lath retained austenite is mainly distributed along the lath ferrite. As the annealing temperature increases, the lath ferrite recrystallizes and gradually grows into the blocky (equiaxed) shape, leading to a decrease in the lath retained austenite content. When the annealing temperature increases to 870 °C, the ferrite content decreases significantly, and the retained austenite is mainly blocky and thin film, distributed at the boundaries of prior austenite grains and between martensite laths, respectively. Different from QQ&P samples, the ferrite and retained austenite in Q&P samples are mainly blocky when the annealing temperature is 780 °C or 810 °C. When the annealing temperature is increased to 870 °C, the microstructures of the Q&P sample are basically the same as that of the QQ&P sample. The 780 °C-QQ&P sample and the 810 °C-QQ&P sample have higher total elongation and product of strength and elongations (PSEs) than their counterpart Q&P samples due to the fact that lath ferrite and retained austenite are conducive to carbon diffusion and carbon homogenization in austenite grains, thereby improving the thermal stability and volume fraction of the retained austenite. In addition, the lath structures can release local stress concentration and delay the formation of voids and microcracks. The difference of mechanical properties between QQ&P samples and Q&P samples decreases with the increase in the annealing temperature. The results show that the low annealing temperature combined with prequenching-Q&P heat treatments can significantly improve the elongation and PSE of Q&P steel.Nonwoven geotextiles are geosynthetic products that are highly susceptible to ultraviolet degradation because light can reach a large area of the material due to its fiber arrangement. Even with additives, which delay the degradation process, material decomposition still occurs, and therefore the product's long-term durability can be affected. In this paper, the mechanical and thermal behavior of a commercial nonwoven polyester geotextile subjected to accelerated ultraviolet aging tests were evaluated. The deterioration was evaluated by comparing the physical properties (mass per unit area, thickness, and tensile strength) and thermal behavior (thermogravimetry-TG, thermomechanical analysis-TMA, and differential scanning calorimetry-DSC) before and after exposure times of 500 h and 1000 h. The results showed that the ultraviolet aging tests induced some damage in the polyester fibers, leading to the deterioration of their tensile strength. For 1000 h of exposure, in which the reduction was larger, scanning electron microscopy (SEM) found some superficial disruption of the fibers, indicative of damage. TG and DSC could not capture the effects of UV radiation on polymer degradation, unlike TMA. This latter technique was effective in showing the differences between specimens before and after UV exposure.A zeroth-order, non-diffracting Bessel beam, generated by picosecond laser pulses (1064 nm, 10 Hz, 30 ps) through an axicon, was utilized to perform pulse energy-dependent (12 mJ, 16 mJ, 20 mJ, 24 mJ) laser ablation of silver (Ag) substrates in air. The fabrication resulted in finger-like Ag nanostructures (NSs) in the sub-200 nm domain and obtained structures were characterized using the FESEM and AFM techniques. Subsequently, we employed those Ag NSs in surface-enhanced Raman spectroscopy (SERS) studies achieving promising sensing results towards trace-level detection of six different hazardous materials (explosive molecules of picric acid (PA) and ammonium nitrate (AN), a pesticide thiram (TH) and the dye molecules of Methylene Blue (MB), Malachite Green (MG), and Nile Blue (NB)) along with a biomolecule (hen egg white lysozyme (HEWL)). The remarkably superior plasmonic behaviour exhibited by the AgNS corresponding to 16 mJ pulse ablation energy was further explored. To accomplish a real-time application-oriented understanding, time-dependent studies were performed utilizing the AgNS prepared with 16 mJ and TH molecule by collecting the SERS data periodically for up to 120 days. The coated AgNSs were prepared with optimized gold (Au) deposition, accomplishing a much lower trace detection in the case of thiram (~50 pM compared to ~50 nM achieved prior to the coating) as well as superior EF up to ~108 (~106 before Au coating). Additionally, these substrates have demonstrated superior stability compared to those obtained before Au coating.In this paper, a polycrystalline diamond was synthesized by the direct detonation method using graphite as the carbon source. By comparing the numbers of the obtained diamond particles and the original graphite particles, it was found that when the graphite phase transformed into the polycrystalline diamond during the detonation process, a single graphite particle would form multiple diamond nuclei, and the nuclei would grow simultaneously to form polycrystals. Accordingly, a validation experiment was designed, which added different ratios of inert additives while keeping the ratio of graphite to hexogen (RDX) unchanged. It was found that increasing the ratio of inert additives within a certain range could increase the grain size of a polycrystalline diamond, which is consistent with the obtained polycrystalline mechanism.An investigation into the addition of different weight percentages of Fe3O4 nanoparticles to find the optimum wt.% and its effect on the microstructure, thermal, magnetic, and electrical properties of aluminum matrix composite was conducted using the powder metallurgy method. The purpose of this research was to develop magnetic properties in aluminum. Based on the obtained results, the value of density, hardness, and saturation magnetization (Ms) from 2.33 g/cm3, 43 HV and 2.49 emu/g for Al-10 Fe3O4 reached a maximum value of 3.29 g/cm3, 47 HV and 13.06 emu/g for the Al-35 Fe3O4 which showed an improvement of 41.2%, 9.3%, and 424.5%, respectively. The maximum and minimum coercivity (Hc) was 231.87 G for Al-10 Fe3O4 and 142.34 G for Al-35 Fe3O4. Moreover, the thermal conductivity and electrical resistivity at a high weight percentage (35wt.%) were 159 w/mK, 9.9 × 10-4 Ω·m, and the highest compressive strength was 133 Mpa.The potential for site-specific, process-parameter control is an attribute of additive manufacturing (AM) that makes it highly attractive as a manufacturing process. The research interest in the functionally grading material properties of numerous AM processes has been high for years. However, one of the issues that slows developmental progress in this area is process planning. It is not uncommon for manual programming methods and bespoke solutions to be utilized for site-specific control efforts. This article presents the development of slicing software that contains a fully automated process planning approach for enabling through-thickness, process-parameter control for a range of AM processes. The technique includes the use of parent and child geometries for controlling the locations of site-specific parameters, which are overlayed onto unmodified toolpaths, i.e., a vector-based planning approach is used in which additional information, such as melt pool size for large-scale metal AM processes, is assigned to the vectors. This technique has the potential for macro- and micro-structural modifications to printed objects. A proof-of-principle experiment is highlighted in which this technique was used to generate dynamic bead geometries that were deposited to induce a novel surface embossing effect, and additional software examples are presented that highlight software support for more complex objects.In this paper, a method to control the lime reaction by different slaking conditions is proposed to reduce the occurrence of cracks in newly repaired earthen city walls. The effects and mechanisms of the slaking time (0 h, 12 h, 24 h, 48 h and 72 h), lime content (10%, 15% and 20%), and moisture content (14%, 18% and 22%) on the cracking and mechanical properties of lime soil were analyzed by the test results of surface cracks, triaxial compression, particle gradation, pH value, X-ray diffraction and scanning electron microscope. The results show that proper slaking of lime soil specimens can reduce surface cracks and improve mechanical properties. After 12 h of appropriate slaking, the crack rate of the lime soil with 20% content decreased by 97.13%, the cohesion increased by 20.27%, and the internal friction angle decreased by 11.27%. However, the mechanical properties decreased when the slaking time was too long. After 72 h of slaking, the cohesion of 20% lime soil decreased by 8.21% and the internal friction angle increased by 2.82%. Further analysis shows that the appropriate slaking conditions can regulate the reaction rate and alkali environment, control the lime produced cementitious substances, improve the particle gradation and further reduce the occurrence of surface cracks. These results provide a basis for the restoration technology of newly repaired earthen city walls.The removal of Cd2+, Zn2+ and Ni2+ from metal solutions onto waste toner power (WTP) was investigated. The influence of parameters such as pH, contact time, initial metal concentration and adsorbent dosage was studied in batch adsorption experiments. Batch equilibrium experiments showed that the highest removal efficiency for Zn2+ and Cd2+ occurs at pH 7, while pH 5 is the most suitable for Ni2+ removal. The amount of metal removed (mg/g) improved when increasing the initial concentration, and sorption of heavy metals reached equilibrium in 24 h. see more Metals' uptake increased with increasing adsorbent dosage. The adsorption isotherms of Zn2+, Cd2+ and Ni2+ onto WTP fit the Langmuir better than the Freundlich model with correlation coefficient R2 values ranging from 0.998 to 0.968 and 0.989 to 0.881, respectively. The data showed that the maximum adsorption capacity of heavy metals, amax, ranged from 2.42 to 1.61 mg/g, from 6.22 to 2.01 mg/g and from 3.49 to 2.56 mg/g for Ni2+, Zn2+ and Cd2+, respectively, with the three WTPs used in this study.