Electrochemical adsorption involving hydrogen on mixed Pd2Pt nanostructures

Based on these results, a model for the arrays of amylopectin and amylose molecules within semi-crystalline lamellas of rice starch granules was proposed. These results will enable plant breeders to produce rice with desirable ECQs based on better understandings of the importance of starch fine molecular structures in determining starch gelatinization property. In this study, a new type of graft modified flocculant (CS-g-PAD) was copolymerized of AM, DAC and chitosan (CS) by microwave assisted initiation and used for sludge conditioning and dewatering. The effect of reaction conditions on microwave assisted copolymerization was investigated and their optimal values were obtained by orthogonal experiments. The structure and chemical properties of CS-g-PAD were characterized and the results indicated that microwave assisted polymerization can cause the generated side polymer chain of PAD to react with the -NH2 active group in CS. Thus, the graft copolymerization occurred at amino group connected with C2 site. Compared with CCPAM, PAD and CS, the synthesized CS-g-PAD exhibits superior sludge dewatering performance (FCMC 72.1%, SRF 4.5 × 1012 m/kg, d50 679.556 μm, Df 1.72, floc sedimentation rate 5.72 cm/min) in a wide pH range (pH = 3.5-9.5). Because CS-g-PAD contains a large amount of cationic DAC and positively charged CS as well as many functional groups on CS, it increases the charge neutralization, electrical patching and adsorption capability. Additionally, the grafting PAD on CS has a good extension in solution to increase its adsorption bridging effect. The new grafted CS-g-PAD is promising and has great practical application value in sludge dewatering and condition. Virus-based biocontrol technologies represent sustainable alternatives to pesticides and insecticides. Phytoplasmas are prokaryotic plant pathogens causing severe losses to crops worldwide. Novel approaches are needed since insecticides against their insect vectors and rogueing of infected plants are the only available strategies to counteract phytoplasma diseases. A new iflavirus, named EVV-1, has been described in the leafhopper phytoplasma vector Euscelidius variegatus, raising the potential to use virus-based application strategies against phytoplasma disease. Here transmission routes of EVV-1 are characterized, and localization within the host reveals the mechanism of insect tolerance to virus infection. Both vertical and horizontal transmission of EVV-1 occur and vertical transmission was more efficient. The virus is systemic and occurs in all life-stages, with the highest loads measured in ovaries and first to third instar nymphs. The basic knowledge gained here on the biology of the virus is crucial for possible future application of iflaviruses as biocontrol agents. Diabetic retinopathy (DR) is considered as a diabetes-related complication that can lead to severe visual impairments. By 2030, it is expected that 1 in 5 adults will suffer from the disease. Suitable animal models for chronic DR are essential for a better understanding of the pathophysiology and to further develop new treatments. The Ins2Akita mouse is a type 1 diabetes model that shows signs of both early and late stages of DR, including pericyte loss, increased vascular permeability, increased acellular capillaries and neovascularization. To further characterize DR in the Ins2Akita mouse model, we have evaluated the protein levels of the angiogenesis inducers vascular endothelial growth factor (VEGF) and placental growth factor (PlGF) and the angiogenesis inhibitor pigment epithelium-derived factor (PEDF). Additionally, we have analyzed the protein expression profile of the glial markers ionized calcium binding adaptor molecule 1 (Iba1) and glial fibrillary acidic protein (GFAP) as well as of the chemokine monocyte chemoattractant protein 1 (MCP-1). In this study we demonstrate that, with disease progression, there is the development of an inflammatory response and an unbalanced expression of pro- and antiangiogenic factors in the neural retina and in the retinal pigment epithelium (RPE) of Ins2Akita mice. Therefore, our data provide support for the diabetic retinopathy features detected in the Ins2Akita retina, reflecting what is observed in the human pathology. OBJECTIVES When managing deep carious lesions, dentists can maintain pulp vitality via (1) avoiding pulp exposure and complications by performing selective (SE) instead of non-selective (NS) carious tissue removal, and/or (2) treat exposed pulps by direct capping with mineral-trioxide-aggregate (MTA) instead of calcium hydroxide (CH). We assessed the cost-effectiveness of SE vs. NS combined with direct pulp capping using MTA vs. CH. METHODS A mixed public-private-payer perspective within German healthcare was applied. We modeled a permanent molar with a deep carious lesion and a vital asymptomatic pulp. The lesion was treated by SE/NS and, in case of exposure, direct pulp capping using MTA/CH. The tooth was followed over the lifetime of an initially 30-year-old patient using Markov-models, informed by pairwise and Bayesian network meta-analyses and further data sources. The primary health outcome was tooth-retention time. Costs were derived from German fee item catalogues, combined with micro-costing. Monte-Carlo micro-simulation was performed, and uncertainty introduced via probabilistic and univariate sensitivity analyses. Value-of-information-analysis (VOI) was performed to quantify the value of further research. RESULTS SE and, in case of pulp exposure, MTA had a high chance (>95 %) of being cost-effective, with teeth being retained for 37.37 years at costs of 2140 Euro in mean. Alternative strategies were both more costly and less effective; this ranking was robust in sensitivity analyses. The VOI was 1.18 Euro per treated case and 12.86 million Euro on population-level. CONCLUSION Selective carious tissue removal and, in case of pulp exposure, direct capping with MTA was the most cost-effective strategy. selleck chemical CLINICAL SIGNIFICANCE Avoiding pulp exposure was more relevant for cost-effectiveness than how the exposed pulp was managed. Overall differences remain limited, though, and dentists may want to tailor treatment strategies according to their expertise and patients' expectations.